JudasIscariot: I tried Fallout 1 on it and I can't believe they messed that up. It is horribad.
I remember playing a downloaded copy of Fallout, purchased directly from Interplay using a technology called Stream Theory (many years ago; the technology is now dead). It turned out that I was unable to save my game, so my money was refunded.
Jagged Alliance 2 on Steam had similar issues for over a year, which were only fixed a few months ago.
Gametap's inability to support older games is not that unusual (though its complete inability to deal with 64-bit systems is!). I think it highlights how well GoG is doing with its handling of older games.
Back to the original topic though... if I was a user on 32-bit Windows in the USA, I think I'd be prepared to suffer the user interface in order to play the games they have, at the reasonably low prices they're offering.
Try downloading Gametap and give the free stuff a burl - they have their game list online, so you can decide later on whether you're prepared to part with your money.